That's the thing, my system is (and remains, fingers crossed) basically completely stable. It's just the 'POST'ing that's the problem.
I really don't want to have to start twiddling ignorantly with voltages in UEFI, and while there's any number of forum Reddit posts on this the signal to noise ratio is abysmal.
I might just downclock to 3200 and see how that goes. But I'm annoyed to be in this situation at all.
Pull and re-seat the RAM, dust out the entire rig, reset CMOS, confirm booting at 2666Mhz, then try XMP1, then XMP2 if XMP1 is sharty at 3600. I had a b550 that didn’t like pushing 3600/c16 at XMP1 and bizarrely that’s the same exact profile as XMp2, voltage and all, though perhaps it gooses the vDiMM at post, I dunno. Reboot and let it rip.
Once it posts and you’re aware that drives are healthy and no major hardware changes are happening enable Fast Boot if not already on, or disable fast boot for a full count on boot (don’t turn off SMART monitoring in your OS of choice). Note: I’ve not delved into the Reddit Miasma but if you’re seeing dying VRMs so early it’s maybe a mobo RMA session waiting to happen, but poke it with a stick first.
Reseat everything. Take your OS drive out too if you care about its data integrity and just boot an install thumb or any other clone if you’d like to get into an OS to verify timings, temps, etc with HWInfo64–strongly recommended.
This seems fixable. Also, disable or only at most auto PBO your CPU once you restore normal board power, then work backwards from a working system there. I suspect that your undervoltt first and foremost is showing its limits. Don’t be shy about reseating your CPU when I recommend to re-seat everything.
Edit: double check the seating of your ATX 12V pin makeups. Top left of most boards.